Remote Control by Steric Effects

descriptionPublicationkeyboard_double_arrow_right Article 21 Feb 2014 English Publisher:American Association for the Advancement of Science (AAAS)Journal:Science, volume 343, pages 850-851 (issn: 0036-8075, eissn: 1095-9203,

Authors: Naoto Chatani; Mamoru Tobisu;

doi: 10.1126/science.1250335

Remote Control by Steric Effects

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Abstract

A rhodium-catalyzed reaction places a silicon substituent on the site farthest away from the largest group present on an aromatic ring. [Also see Research Article by Cheng and Hartwig ]

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Osaka University
Japan

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