A General Synthetic Procedure for Heteropolyniobates
Copyright policy ) May, Nyman; François, Bonhomme; Todd M, Alam; Mark A, Rodriguez; Brian R, Cherry; James L, Krumhansl; Tina M, Nenoff; +1 Authors
May, Nyman; François, Bonhomme; Todd M, Alam; Mark A, Rodriguez; Brian R, Cherry; James L, Krumhansl; Tina M, Nenoff; Amy M, Sattler;
A General Synthetic Procedure for Heteropolyniobates
The heteropolyanions of W, Mo, and V, which have found numerous applications, are formed simply by acidification of solutions of their oxoanions. Under similar conditions, these oxoanion precursors are not available for Nb, and Nb-oxo chemistry is dominated by formation of the Lindquist ion [Nb 6 O 19 ] 8– only. However, heteropolyniobate formation is favored in hydrothermal reactions of aqueous, alkaline precursor mixtures. Here we give two examples of heteropolyniobates formed by this general reaction type: K 12 [Ti 2 O 2 ][SiNb 12 O 40 ]·16H 2 O [1], which contains chains of silicododecaniobate Keggin ions, and Na 14 [H 2 Si 4 Nb 16 O 56 ]·45.5H 2 O [ 2 ], a new heteropolyanion structure type.
- Sandia National Laboratories United States
- Sandia National Laboratories California United States
selected citations These citations are derived from selected sources.This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).299 popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.Top 1% influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).Top 1% impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.Top 10%
selected citations
Citations provided by BIP!
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
Citations provided by BIP!popularityPopularity provided by BIP!
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
Popularity provided by BIP! 299
Top 1%
Top 1%
Top 10%
Fields of Science (7) View all
This action will publish the selected files and record in Zenodo. Are you sure you want to proceed?