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Kinetic theory and transport phenomena for a dumbbell model under nonisothermal conditions

Authors: Hans Christian Öttinger; Fabrizio Petrillo;

Kinetic theory and transport phenomena for a dumbbell model under nonisothermal conditions

Abstract

A Hookean dumbbell model for polymers in dilute solutions undergoing homogeneous flow is generalized to include arbitrary imposed temperature profiles. In order to obtain the ‘‘nonisothermal diffusion equation’’ for the probability density in polymer configuration space we generalize the approach of Schieber and Ottinger [J. Chem. Phys. 89, 6972–6981 (1988)] to Brownian motion out of equilibrium. In addition, we derive the polymer contributions to the mass‐flux vector, stress tensor and heat‐flux vector by means of the kinetic theory approach of Curtiss and Bird [Adv. Polym. Sci. 125, 1–101 (1996)] for the case of a slowly varying temperature gradient, and we find coupled constitutive equations for the mass, momentum and energy fluxes. For a simple steady shear flow it is then possible to calculate the heat‐flux vector explicitly, at least for small temperature gradients and shear rates. We compare our approach and results with previous works on this subject, and we finally discuss some extensions.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
16
Average
Top 10%
Top 10%
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