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On the rheology of filled polymers

Authors: A. I. Leonov;

On the rheology of filled polymers

Abstract

This paper develops a rheological model for flow of polymer compounds highly filled by small interacting (attractive) particles. The properties of the particle phase in the compound are described by introducing a viscoelastic ‘‘particle mode’’ with an additional kinetic equation which describes the processes of rupture and restoration of flocs of particles. The elastic deformations in the particle mode are assumed to be small enough to consider the geometrical nonlinearities as second‐order effects. The rheological behavior of the polymer matrix is modeled by means of nonlinear viscoelasticity, as in the case of pure polymer melts. It was shown that all the basic features of the yield‐like and thixotropic behavior of the filled polymer compounds, including the appearance of yield values in steady state flows, stress overshoots in start up flows and effects of ‘‘frozen memory’’ during relaxation could be described by this approach without using the mathematical yield criteria. Some preliminary comparisons of the theory with steady state data are also demonstrated.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
105
Top 10%
Top 1%
Top 10%
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