
pmid: 18276548
Data are reported for the dielectric, piezoelectric, electrostrictive, and ferroelectric properties of potassium-substituted sodium bismuth titanate, [(K(x)Na(1-x))(0.5)Bi(0.5)]TiO3. For the morphotropic phase boundary composition x = 0.2, relaxor-type behavior was observed at room temperature with piezoelectric (effective d(333) = 325 x 10(-12) m/V) and ferroelectric properties (P(R) = 25 microC/cm(2), E(C) = 30 kV/cm). A transition to a relatively frequency-independent, diffuse phase transformation region occurred with increasing temperature, with no remanent strain or coercive field. Above the transition temperature, the field-induced strain was consistent with contributions from electrostriction and field induced piezoelectricity (M(3333) = 1.9 x 10(-16) m2/V2 and d333 = 81 x 10(-12) m/V at 100 degrees C). Information is given for the temperature dependence of properties, e.g., 0.14% strain induced at 50 kV/cm at 200 degrees C. Higher potassium content x = 0.6 stabilized the ferroelectric piezoelectric region to temperatures above 200 degrees C, with a relatively stable d(333) = 150-145 x 10-12 m/V between 25 degrees C and 200 degrees C. Pb-free KNBT ceramics appear competitive with PZT, especially for higher temperature electromechanical applications.
Ceramics, Transducers, Reproducibility of Results, Acoustics, Equipment Design, Sensitivity and Specificity, Elasticity, Equipment Failure Analysis, Electromagnetic Fields, Materials Testing, Electric Impedance, Electrochemistry, Stress, Mechanical
Ceramics, Transducers, Reproducibility of Results, Acoustics, Equipment Design, Sensitivity and Specificity, Elasticity, Equipment Failure Analysis, Electromagnetic Fields, Materials Testing, Electric Impedance, Electrochemistry, Stress, Mechanical
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