Diaquabis[2-(4-bromophenyl)acetato]bis(N4,N4-dimethylpyridin-4-amine)copper(II)

descriptionPublicationkeyboard_double_arrow_right Article 05 Sep 2009Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Structure Reports Online, volume 65, pages m1163-m1163 (eissn: 1600-5368,

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Authors: Yong-Ming Cui; Xi-Bin Dai; Ru-Hua Zha; Qing-Fu Zeng;

doi: 10.1107/s1600536809034461

Diaquabis[2-(4-bromophenyl)acetato]bis(N4,N4-dimethylpyridin-4-amine)copper(II)

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Abstract

In the title compound, [Cu(C(8)H(6)BrO(2))(2)(C(7)H(10)N(2))(2)(H(2)O)(2)], the Cu(II) atom (site symmetry [Image: see text]) adopts a Jahn–Teller-distorted trans-CuN(2)O(4) octahedral coordination, with the aqua O atoms in axially extended sites. An intramolecular O—H⋯O hydrogen bond helps to establish the conformation and an intermolecular O—H⋯O hydrogen bond is seen in the crystal packing.

Related Organizations

Ministry of Education of the People's Republic of China
China (People's Republic of)

Keywords

Metal-Organic Papers, Crystallography, QD901-999

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