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Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 22 Apr 2009Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Structure Reports Online, volume 65, pages m557-m557 (eissn: 1600-5368,

Authors: Wei Wang; Yong-Miao Shen;

doi: 10.1107/s160053680901438x

pmid: 21583790

pmc: PMC2977604

Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium

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Abstract

The mol-ecule of the title compound, [NaNi(C(18)H(18)N(2)O(4))(C(2)N(3))(H(2)O)], is approximately planar, with a maximum deviation from the mol-ecular plane of 0.770 (5) Å. The coordination environment of the Ni(2+) ion is distorted square-planar and it is N(2)O(2) coordinated by the 6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Na(+) atom is chelated by the four O atoms of the Schiff base ligand, a water ligand and a dicyanamide anion. The structure displays inter-molecular O-H⋯N hydrogen bonding.

Related Organizations

Shaoxing University
China (People's Republic of)
Yancheng Institute of Technology
China (People's Republic of)

Keywords

Metal-Organic Papers

22 Research products, page 1 of 3

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