Four-centre hydrogen bonds: a triethanolamine–triethanolamine oxide complex

descriptionPublicationkeyboard_double_arrow_right Article 19 Jul 2002Publisher:International Union of Crystallography (IUCr)Journal:Acta Crystallographica Section E Structure Reports Online, volume 58, pages o851-o852 (eissn: 1600-5368,

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Authors: Tim Kemmitt; Graeme J. Gainsford; Peter J. Steel; Jan Wikaira;

doi: 10.1107/s1600536802012175

Four-centre hydrogen bonds: a triethanolamine–triethanolamine oxide complex

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Abstract

The title complex, ((HOCH2CH2)3N)(HOCH2CH2)3NO) or C6H15NO4·C6H15NO3, has the amine–oxide O atom trifurcated by a trigonal `cap' of hydrogen bonds to the hydroxyl H atoms of the triethanolamine lying on the same threefold axis. The amine–oxide hydroxyl H atoms are hydrogen bonded to three adjacent triethanolamine O atoms, completing a three-dimensional polymeric network.

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