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https://doi.org/10.1103/rppd-v...
Article . 2026 . Peer-reviewed
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Article . 2025
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Polarization dependency in resonant inelastic x-ray scattering

Authors: Michelangelo Tagliavini; Fabian Wenzel; Maurits W. Haverkort;

Polarization dependency in resonant inelastic x-ray scattering

Abstract

Resonant Inelastic X-Ray Scattering (RIXS) is a well-established tool for probing excitations in a wide range of materials. The measured spectra strongly depend on the scattering geometry, via its influence on the polarization of the incoming and outgoing light. By employing a tensor representation of the 4-point response function that governs the RIXS intensity, we disentangle the experimental geometry from the intrinsic material properties. In dipole-dipole RIXS processes and low-symmetry crystals, up to 81 linearly independent fundamental spectra can be measured as a function of light polarization. However, for crystals or molecules with symmetry, the number of independent fundamental spectra that define the RIXS tensor is significantly reduced. This work presents a systematic framework for determining the number of fundamental spectra and expressing the RIXS tensor in terms of these fundamental components. Given a specific experimental geometry, the measured spectrum can be represented as a linear combination of these fundamental spectra. To validate our approach, we performed calculations for different point group symmetries, both with and without an applied magnetic field. Within the same framework, we derived expressions for powder spectra in momentum-independent processes and spectra obtained using Bragg spectrometers. This formalism provides a valuable toolkit for optimizing experiment planning, data interpretation, and RIXS simulation.

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Keywords

Strongly Correlated Electrons (cond-mat.str-el), Strongly Correlated Electrons, FOS: Physical sciences

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Top 10%
Average
Average
Green