
We study the role of the attractive intermolecular forces in the viscous regime of a simple glass-forming liquid by using computer simulations. To this end, we compare the structure and the dynamics of a standard Lennard-Jones glass-forming liquid model with and without the attractive tail of the interaction potentials. The viscous slowing down of the two systems are found to be quantitatively and qualitatively different over a broad density range, whereas the static pair correlations remain close. The common assumption that the behaviour of dense nonassociated liquids is determined by the short-ranged repulsive part of the intermolecular potentials dramatically breaks down for the relaxation in the viscous liquid regime.
4 pages, 3 figures
[PHYS.COND.CM-SM] Physics [physics]/Condensed Matter [cond-mat]/Statistical Mechanics [cond-mat.stat-mech], Statistical Mechanics (cond-mat.stat-mech), FOS: Physical sciences, Disordered Systems and Neural Networks (cond-mat.dis-nn), Condensed Matter - Disordered Systems and Neural Networks, Condensed Matter - Statistical Mechanics, [PHYS.COND.CM-DS-NN] Physics [physics]/Condensed Matter [cond-mat]/Disordered Systems and Neural Networks [cond-mat.dis-nn]
[PHYS.COND.CM-SM] Physics [physics]/Condensed Matter [cond-mat]/Statistical Mechanics [cond-mat.stat-mech], Statistical Mechanics (cond-mat.stat-mech), FOS: Physical sciences, Disordered Systems and Neural Networks (cond-mat.dis-nn), Condensed Matter - Disordered Systems and Neural Networks, Condensed Matter - Statistical Mechanics, [PHYS.COND.CM-DS-NN] Physics [physics]/Condensed Matter [cond-mat]/Disordered Systems and Neural Networks [cond-mat.dis-nn]
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