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Physical Review Letters
Article . 2009 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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https://dx.doi.org/10.48550/ar...
Article . 2009
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Nonperturbative Effect of Attractive Forces in Viscous Liquids

Authors: Berthier, Ludovic; Tarjus, Gilles;

Nonperturbative Effect of Attractive Forces in Viscous Liquids

Abstract

We study the role of the attractive intermolecular forces in the viscous regime of a simple glass-forming liquid by using computer simulations. To this end, we compare the structure and the dynamics of a standard Lennard-Jones glass-forming liquid model with and without the attractive tail of the interaction potentials. The viscous slowing down of the two systems are found to be quantitatively and qualitatively different over a broad density range, whereas the static pair correlations remain close. The common assumption that the behaviour of dense nonassociated liquids is determined by the short-ranged repulsive part of the intermolecular potentials dramatically breaks down for the relaxation in the viscous liquid regime.

4 pages, 3 figures

Keywords

[PHYS.COND.CM-SM] Physics [physics]/Condensed Matter [cond-mat]/Statistical Mechanics [cond-mat.stat-mech], Statistical Mechanics (cond-mat.stat-mech), FOS: Physical sciences, Disordered Systems and Neural Networks (cond-mat.dis-nn), Condensed Matter - Disordered Systems and Neural Networks, Condensed Matter - Statistical Mechanics, [PHYS.COND.CM-DS-NN] Physics [physics]/Condensed Matter [cond-mat]/Disordered Systems and Neural Networks [cond-mat.dis-nn]

  • BIP!
    Impact byBIP!
    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    144
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
144
Top 10%
Top 10%
Top 1%
Green
bronze