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https://doi.org/10.1103/physre...
Article . 2016 . Peer-reviewed
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Gelation in mixtures of polymers and bidisperse colloids

Authors: Jacinta C. Conrad; Rahul Pandey;

Gelation in mixtures of polymers and bidisperse colloids

Abstract

We investigated the effects of varying the volume fraction of large particles (r) on the linear rheology and microstructure of mixtures of polymers and bidisperse colloids, in which the ratio of the small and large particle diameters was α=0.31 or α=0.45. Suspensions formulated at a total volume fraction of ϕ_{T}=0.15 and a constant concentration of polymer in the free volume c/c^{*}≈0.7 contained solid-like gels for small r and fluids or fluids of clusters at large r. The solid-like rheology and microstructure of these suspensions changed little with r when r was small, and fluidized only when r>0.8. By contrast, dense suspensions with ϕ_{T}=0.40 and α=0.31 contained solid-like gels at all concentrations of large particles and exhibited only modest rheological and microstructural changes upon varying the volume fraction of large particles. These results suggest that the effect of particle-size dispersity on the properties of colloid-polymer mixtures are asymmetric in particle size and are most pronounced near a gelation boundary.

Related Organizations
Keywords

Microscopy, Confocal, Suspensions, Polymers, Static Electricity, Polymethyl Methacrylate, Viscoelastic Substances, Particle Size, Rheology, Gels

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Top 10%
Average
Average
hybrid