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pmid: 26871125
We investigated the effects of varying the volume fraction of large particles (r) on the linear rheology and microstructure of mixtures of polymers and bidisperse colloids, in which the ratio of the small and large particle diameters was α=0.31 or α=0.45. Suspensions formulated at a total volume fraction of ϕ_{T}=0.15 and a constant concentration of polymer in the free volume c/c^{*}≈0.7 contained solid-like gels for small r and fluids or fluids of clusters at large r. The solid-like rheology and microstructure of these suspensions changed little with r when r was small, and fluidized only when r>0.8. By contrast, dense suspensions with ϕ_{T}=0.40 and α=0.31 contained solid-like gels at all concentrations of large particles and exhibited only modest rheological and microstructural changes upon varying the volume fraction of large particles. These results suggest that the effect of particle-size dispersity on the properties of colloid-polymer mixtures are asymmetric in particle size and are most pronounced near a gelation boundary.
Microscopy, Confocal, Suspensions, Polymers, Static Electricity, Polymethyl Methacrylate, Viscoelastic Substances, Particle Size, Rheology, Gels
Microscopy, Confocal, Suspensions, Polymers, Static Electricity, Polymethyl Methacrylate, Viscoelastic Substances, Particle Size, Rheology, Gels
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influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
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