
We show how attractive interactions dramatically influence emulsion rheology. Unlike the repulsive case, attractive emulsions below random close packing, RCP, can form soft gel-like elastic solids. However, above RCP, attractive and repulsive emulsions have similar elasticities. Such compressed attractive emulsions undergo an additional shear-driven relaxation process during yielding. Our results suggest that attractive emulsions begin to yield at weak points through the breakage of bonds, and, above RCP, also undergo droplet configurational rearrangements.
Condensed Matter - Materials Science, Fluid Dynamics (physics.flu-dyn), Soft Condensed Matter (cond-mat.soft), Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, Physics - Fluid Dynamics, Condensed Matter - Soft Condensed Matter
Condensed Matter - Materials Science, Fluid Dynamics (physics.flu-dyn), Soft Condensed Matter (cond-mat.soft), Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, Physics - Fluid Dynamics, Condensed Matter - Soft Condensed Matter
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