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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Physical Review Earrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Physical Review E
Article . 2008 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
CNR ExploRA
Article . 2008
Data sources: CNR ExploRA
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Steric effects in dispersion forces interactions

Authors: SONNET A. M; VIRGA, EPIFANIO GUIDO GIOVANNI;

Steric effects in dispersion forces interactions

Abstract

Classically, there have been two different ways to obtain mean-field theories for liquid crystals. One is based on short-range repulsive steric forces and the other on long-range attractive dispersion forces. In the former approach, it is the anisotropic shape of the molecules that leads to the anisotropic interaction, and in the latter it is the anisotropy of the molecular polarizability. In real molecules both causes of anisotropy can be expected to contribute to the effective interaction, and so it is desirable to assess the combined effect of anisotropic long-range attraction and short-range repulsion. Here we present an avenue to this end. We start from dispersion forces interactions and combine them with hard-core repulsions in a formal theory, whose crucial element is the steric tensor, a fourth-rank tensor depending on the anisotropy of the interacting molecules. This tensor can be determined analytically for a special class of molecular shapes.

Keywords

Physics, LIQUID CRYSTALS, DISPERSION FORCES, 500, STERIC INTERACTIONS, 530

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
16
Average
Average
Top 10%
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