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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1993 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Activated decay rate: Finite-barrier corrections

Authors: , Melnikov;

Activated decay rate: Finite-barrier corrections

Abstract

The activated escape of an underdamped Brownian particle out of a deep potential well is characterized by weak friction \ensuremath{\gamma}\ensuremath{\ll}\ensuremath{\omega} (\ensuremath{\gamma} is the coefficient of friction and \ensuremath{\omega} is a typical frequency of the intrawell motion) and by a large barrier height ${\mathit{U}}_{0}$\ensuremath{\gg}T (${\mathit{U}}_{0}$ is the barrier height and T is the temperature). The approach developed previously to calculate the decay rate is based on the derivation of an integral equation and enables one to sum up an infinite series in powers of the ratio \ensuremath{\gamma}${\mathit{U}}_{0}$/T\ensuremath{\omega}\ensuremath{\sim}1 contributing to the preexponential factor of the Arrhenius law. In the present paper it is shown that the leading correction to the above result comes from the slowing down of the particle motion near the top of the barrier and is of the order of (T/${\mathit{U}}_{0}$) ln(${\mathit{U}}_{0}$/T). To calculate it explicitly, one needs to find a correction to the kernel of the above-mentioned integral equation. Beyond the leading-logarithmic approximation, two different factors contribute corrections of the order of T/${\mathit{U}}_{0}$\ensuremath{\sim}\ensuremath{\gamma}/\ensuremath{\omega}. The noise-induced effects in the barrier crossing-recrossing by particles in a narrow energy range \ensuremath{\varepsilon}\ensuremath{\sim}\ensuremath{\gamma}T/\ensuremath{\omega} can be easily incorporated into the general scheme of the calculations. On the other hand, a more accurate derivation of the kernel of the integral equation is required to take into account small variations of the intrawell particle motion caused by variations of the particle energy on the scale T\ensuremath{\ll}${\mathit{U}}_{0}$ under the effects of friction and thermal noise. The proposed consistent expansion in terms of the small parameters of the problem provides an effective approach to a quantitative investigation of the turnover behavior in the Kramers problem. For the regime of an intermediate-to-strong friction, the finite-barrier corrections can be neglected, since, for typical barrier shapes, they are always small.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
52
Top 10%
Top 10%
Top 10%
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