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https://doi.org/10.1103/physre...
Article . 2021 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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https://dx.doi.org/10.48550/ar...
Article . 2021
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Droplet condensation in the lattice gas with density functional theory

Authors: Maeritz, Manuel; Oettel, Martin;

Droplet condensation in the lattice gas with density functional theory

Abstract

A density functional for the lattice gas (Ising model) from fundamental measure theory is applied to the problem of droplet states in three-dimensional, finite systems. Similar to previous simulation studies, the sequence of droplets changing to cylinders and to planar slabs is found upon increasing the average density $\barρ$ in the system. Owing to the discreteness of the lattice, additional effects in the state curve for the chemical potential $μ(\barρ)$ are seen upon lowering the temperature away from the critical temperature (oscillations in $μ(\barρ)$ in the slab portion and spiky undulations in $μ(\barρ)$ in the cylinder portion as well as an undulatory behavior of the radius of the surface of tension $R_s$ in the droplet region). This behavior in the cylinder and droplet region is related to washed-out layering transitions at the surface of liquid cylinders and droplets. The analysis of the large-radius behavior of the surface tension $γ(R_s)$ gave a dominant contribution $\propto 1/R_s^2$, although the consistency of $γ(R_s)$ with the asymptotic behavior of the radius-dependent Tolman length seems to suggest a weak logarithmic contribution $\propto \ln R_s/R_s^2$ in $γ(R_s)$. The coefficient of this logarithmic term is smaller than a universal value derived with field-theoretic methods.

14 pages, 8 figures, to be published in Phys. Rev. E

Related Organizations
Keywords

Statistical Mechanics (cond-mat.stat-mech), Soft Condensed Matter (cond-mat.soft), FOS: Physical sciences, Condensed Matter - Soft Condensed Matter, Condensed Matter - Statistical Mechanics

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
6
Top 10%
Average
Top 10%
Green