It is well established that the spin-orbit interaction in heavy metal/ferromagnet heterostructures leads to a significant interfacial Dzyaloshinskii-Moriya Interaction (DMI) that modifies the internal structure of magnetic domain walls (DWs) to favor Néel over Bloch type configurations. However, the impact of such a transition on the structure and stability of internal DW defects (e.g., vertical Bloch lines) has not yet been explored. We present a combination of analytical and micromagnetic calculations to describe a new type of topological excitation called a DW Skyrmion characterized by a $360^\circ$ rotation of the internal magnetization in a Dzyaloshinskii DW. We further propose a method to identify DW Skyrmions experimentally using Fresnel mode Lorentz TEM; simulated images of DW Skyrmions using this technique are presented based on the micromagnetic results.