
Using x-ray emission spectroscopy and absorption spectroscopy, it has been possible to directly access the states in the unoccupied conduction bands that are involved with $5f$ and $6d$ covalency in oxidized uranium. By varying the oxidizing agent, the degree of $5f$ covalency can be manipulated and monitored, clearly and irrevocably establishing the importance of $5f$ covalency in the electronic structure of the key nuclear fuel, uranium dioxide.
Physical sciences, Engineering, Chemical sciences, Physical Sciences, Synchrotrons and Accelerators
Physical sciences, Engineering, Chemical sciences, Physical Sciences, Synchrotrons and Accelerators
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