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Physical Review B
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Physical Review B
Article . 2014 . Peer-reviewed
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Broken symmetry induced band splitting in theAg2Gesurface alloy on Ag(111)

Authors: Wang, Weimin; Sohail, Hafiz Muhammad; Osiecki, Jacek; Uhrberg, Roger;

Broken symmetry induced band splitting in theAg2Gesurface alloy on Ag(111)

Abstract

We report a study of the atomic and electronic structures of the ordered ${\mathrm{Ag}}_{2}\mathrm{Ge}$ surface alloy containing ⅓ monolayer of Ge. Low-energy electron diffraction (LEED), scanning tunneling microscopy (STM), and angle-resolved photoelectron spectroscopy (ARPES) data reveal a symmetry breaking of the expected \ensuremath{\surd}3 \ifmmode\times\else\texttimes\fi{} \ensuremath{\surd}3 periodicity, which is established for other ${\mathrm{Ag}}_{2}$$M$ alloys ($M$ = Bi, Sb, Pb, and Sn). The deviation from a simple \ensuremath{\surd}3 \ifmmode\times\else\texttimes\fi{} \ensuremath{\surd}3 structure manifests itself as a splitting of diffraction spots in LEED, as a striped structure with a 6\ifmmode\times\else\texttimes\fi{} periodicity including a distortion of the local hexagonal structure in STM, and as a complex surface band structure in ARPES that is quite different from those of the other ${\mathrm{Ag}}_{2}$$M$ alloys. These results are interesting in view of the differences in the atomic and electronic structures exhibited by different group IV elements interacting with Ag(111). Pb and Sn form \ensuremath{\surd}3 \ifmmode\times\else\texttimes\fi{} \ensuremath{\surd}3 surface alloys on Ag(111), of which ${\mathrm{Ag}}_{2}\mathrm{Pb}$ shows a surface band structure with a clear spin-orbit split. Si and C form silicene and graphene structures, respectively, with linear band dispersions and the formation of Dirac cones as reported for graphene. The finding that ${\mathrm{Ag}}_{2}\mathrm{Ge}$ deviates from the ideal (\ensuremath{\surd}3 \ifmmode\times\else\texttimes\fi{} \ensuremath{\surd}3) ${\mathrm{Ag}}_{2}\mathrm{Sn}$ and ${\mathrm{Ag}}_{2}\mathrm{Pb}$ surface alloys makes Ge an interesting ``link'' between the heavy group IV elements (Sn, Pb) and the light group IV elements (Si, C).

Country
Sweden
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Keywords

Naturvetenskap, Natural Sciences

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
26
Top 10%
Top 10%
Top 10%
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