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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Physical Review Barrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Physical Review B
Article . 2011 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
MPG.PuRe
Article . 2011
Data sources: MPG.PuRe
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Anharmonic effects in the mixed 4f-electron lattice excitations of Pr skutterudites

Authors: Thalmeier, P.;

Anharmonic effects in the mixed 4f-electron lattice excitations of Pr skutterudites

Abstract

The structure of Pr skutterudites provides large cages for the anharmonic rattling motion of the rare-earth guest atom. For suitable composition, their frequency may be nearly degenerate with low-energy crystalline electric-field excitations of localized 4$f$ states. In this case, the anharmonic oscillation of Pr is supplemented by nonadiabatic or vibronic effects due to 4$f$-electron--phonon coupling. This affects the temperature dependence of the effective phonon frequency and the rattling phonon-Raman contribution to NMR and nuclear quadrupole resonance relaxation. Furthermore, dispersive 4$f$-quadrupole excitations originating from intersite quadrupole coupling may exhibit typical anomalies due to mixing with the phonons. A model of anharmonic rattling phonons together with dispersive 4$f$ excitations is introduced to study these effects. It is of particular relevance to Pr(Os${}_{1\ensuremath{-}x}$Ru${}_{x}$)${}_{4}$Sb${}_{12}$, where the degeneracy of 4$f$ excitations and rattling phonons has been identified before.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
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