Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/ https://backend.orbi...arrow_drop_down
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 2000 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
versions View all 2 versions
addClaim

Magnetic properties of hematite nanoparticles

Authors: Bødker, F.; Hansen, M. F.; Koch, C. B.; Lefmann, K.; Mørup, S.;

Magnetic properties of hematite nanoparticles

Abstract

The magnetic properties of hematite $(\ensuremath{\alpha}\ensuremath{-}{\mathrm{Fe}}_{2}{\mathrm{O}}_{3})$ particles with sizes of about 16 nm have been studied by use of M\"ossbauer spectroscopy, magnetization measurements, and neutron diffraction. The nanoparticles are weakly ferromagnetic at temperatures at least down to 5 K with a spontaneous magnetization that is only slightly higher than that of weakly ferromagnetic bulk hematite. At $T\ensuremath{\gtrsim}100\mathrm{K}$ the M\"ossbauer spectra contain a doublet, which is asymmetric due to magnetic relaxation in the presence of an electric field gradient in accordance with the Blume-Tjon model. Simultaneous fitting of series of M\"ossbauer spectra obtained at temperatures from 5 K to well above the superparamagnetic blocking temperature allowed the estimation of the pre-exponential factor in N\'eel's expression for the superparamagnetic relaxation time, ${\ensuremath{\tau}}_{0}=(6\ifmmode\pm\else\textpm\fi{}4)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}\mathrm{s}$ and the magnetic anisotropy energy barrier, ${E}_{\mathrm{bm}}{/k=590}_{\ensuremath{-}120}^{+150}\mathrm{K}.$ A lower value of the pre-exponential factor, ${\ensuremath{\tau}}_{0}{=1.8}_{\ensuremath{-}1.3}^{+3.2}\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}\mathrm{s},$ and a significantly lower anisotropy energy barrier ${E}_{\mathrm{bm}}^{\mathrm{magn}}/k=305\ifmmode\pm\else\textpm\fi{}20\mathrm{K}$ was derived from simultaneous fitting to ac and dc magnetization curves. The difference in the observed energy barriers can be explained by the presence of two different modes of superparamagnetic relaxation which are characteristic of the weakly ferromagnetic phase. One mode involves a rotation of the sublattice magnetization directions in the basal (111) plane, which gives rise to superparamagnetic behavior in both M\"ossbauer spectroscopy and magnetization measurements. The other mode involves a fluctuation of the net magnetization direction out of the basal plane, which mainly affects the magnetization measurements.

Country
Denmark
Keywords

SUPERPARAMAGNETIC PARTICLES, DYNAMICS, FE2O3, MORIN TRANSITION, MOSSBAUER, ALPHA-FE2O3 PARTICLES, OXIDE, TEMPERATURE

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    343
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
343
Top 1%
Top 1%
Top 1%
Green
Related to Research communities