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Explanation for the configurational heat capacity of ordered phases

Authors: Marcel Sluiter; Yoshiyuki Kawazoe;

Explanation for the configurational heat capacity of ordered phases

Abstract

Recently, an intriguing ``W shape'' has been reported for the curve of the configurational heat capacity versus composition. This feature is calculated in ordered phases with various methods. A detailed explanation has not been published, so a brief derivation and explanation of its origin is in order. Within the context of a Bragg-Williams model expressions for the heat capacity are derived. These expressions indicate that the W shape originates from the composition dependence of the order parameter.

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Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Average
Average
Average
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