Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1995 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
versions View all 2 versions
addClaim

Temperature dependence of Raman scattering in stabilized cubic zirconia

Authors: , Cai; , Raptis; , Raptis; , Anastassakis;

Temperature dependence of Raman scattering in stabilized cubic zirconia

Abstract

The temperature dependence of Raman spectra of cubic yttria-stabilized zirconia (YSZ) for three yttria concentrations (10, 15, and 20 wt %) is investigated in the range 40--1470 K. The variation of the spectra with temperature implies that first-order scattering (one-phonon processes) is dominant in this material, providing further evidence that the broad features observed in the spectra are caused mainly by partial lattice disorder rather than by combination (higher-order) processes. The high-temperature phase of YSZ is entirely stable in this range and remains cubic throughout. The temperature-induced frequency shifts of the band at \ensuremath{\sim}600 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ (attributed to the ${\mathit{F}}_{2\mathit{g}}$ zone-center optic mode) are determined for the three different yttria concentrations. Furthermore, using uniaxial stress data as well, the volume contribution to such shifts is calculated and compared to the lattice anharmonicity contribution. It is found that the volume contribution is larger than the total effect (by a factor of about 2) for all three compositions at 300 K, implying that the bonding in cubic YSZ has ionic character.

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    93
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
93
Top 10%
Top 10%
Top 10%
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!