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https://doi.org/10.1103/physre...
Article . 1995 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Surface stress, surface elasticity, and the size effect in surface segregation

Authors: Schmid, M.; Hofer, W.; Varga, P.; Stoltze, Per; Jacobsen, Karsten Wedel; id_orcid 0000-0002-1121-2979; Nørskov, Jens Kehlet; id_orcid 0000-0002-4427-7728;

Surface stress, surface elasticity, and the size effect in surface segregation

Abstract

Surface stress and surface elasticity of low-index fcc surfaces have been studied using effective-medium theory potentials. In addition to total-energy calculations giving stress components and elastic data for the surface as a whole, the use of artificial atoms with modified size allows us to probe the stress and elasticity of individual layers. This method of artificial atoms provides a direct way to study the contribution of atomic size to segregation in alloys as well as the driving force of reconstructions driven by surface stress. As an example, we give a qualitative explanation of the face-dependent segregation of Pt-Ni alloys. We also compare results of these atomic-scale calculations with continuum elasticity.

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Denmark
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Keywords

ENERGY ELECTRON-DIFFRACTION, TRANSITION-METALS, MULTILAYER RELAXATION, FCC METALS, EMBEDDED-ATOM METHOD, COPPER SURFACES, AU(111) SURFACE, SCANNING TUNNELING MICROSCOPY, SANDWICH SEGREGATION, ION-SCATTERING

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    65
    popularity
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    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
65
Top 10%
Top 10%
Top 10%
Green