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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1993 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Analytic approach to the interfacial polarization of heterogeneous systems

Authors: , Fu; , Macedo; , Resca;

Analytic approach to the interfacial polarization of heterogeneous systems

Abstract

We have obtained an analytical solution of Maxwell's equations for a dielectric system of spherical particles in a medium. The system is placed between two parallel electrode plates, subject to a low-frequency alternating potential, and the solution is obtained from the corresponding boundary-value problem for the Green function. All the multipole moments and the electric field are expressed in terms of the applied potential at the electrodes and a matrix which depends on the system configuration. The effective dielectric function is then obtained as an average over the whole sample. For disordered systems, we solve exactly the case of two-particle distributions with short-range correlations and find that the form of the distribution plays a crucial role. In particular, we prove that for spherically symmetric two-particle distributions all multipole moments except dipoles are exactly zero, and the Maxwell-Garnett result, or, equivalently, the Clausius-Mossotti relation for spherical particles, is valid regardless of the particle concentration. Within the two-particle distribution, corrections to the Maxwell-Garnett result can only derive from nonsphericity in the distribution: in such a case, higher multipole moments are generally nonzero and may strongly affect the effective dielectric function. We provide the explicit expressions for all the multipole moments and the effective dielectric function, which can be computed straightforwardly for any given distribution. We show that an iterative unsymmetrical procedure proposed originally by Bruggeman is inconsistent with our results.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
47
Top 10%
Top 10%
Top 10%
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