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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1991 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Surface resistivity and vibrational damping in adsorbed layers

Authors: , Persson;

Surface resistivity and vibrational damping in adsorbed layers

Abstract

I derive a simple relation between the change in dc resistivity \ensuremath{\Delta}\ensuremath{\rho} of a thin metallic film due to adsorption of molecules on the film surface and the electron-hole pair damping (lifetime \ensuremath{\tau}) of the frustrated translations of the adsorbates. From the measured \ensuremath{\Delta}\ensuremath{\rho} for several different adsorbate systems, I deduce the corresponding \ensuremath{\tau}, which ranges from \ensuremath{\sim}${10}^{\mathrm{\ensuremath{-}}12}$ s for chemisorption systems to \ensuremath{\sim}${10}^{\mathrm{\ensuremath{-}}9}$ s for physisorption systems. Theories for the damping of parallel frustrated translations are developed for three limiting cases of the adsorbate-substrate bond; namely, for covalent, ionic, and van der Waals bonds. I study the change in the broadband infrared (ir) light reflectivity caused by the adsorption of molecules on a semi-infinite metal and I discuss the recent ir study by Hirschmugl et al. for the CO-Cu(100) system. Finally, the observation by ir-spectroscopy by Chabal et al. of dipole-forbidden frustrated translations and rotations for H and CO chemisorbed on metals is discussed and the contribution from the excitation of the parallel frustrated translations to the surface resistivity is calculated.

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Powered by OpenAIRE graph
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
260
Top 10%
Top 1%
Top 10%
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