Manifestation of substituent effects in the Auger parameter
Copyright policy )Manifestation of substituent effects in the Auger parameter
The Auger parameter is composed of contributions from both Auger and photoelectron energies; it is held to be a function of only extra-atomic relaxation (i.e., ligand polarization). Its correlation with the Hammett-Taft inductive substituent constant demonstrates this to be true. Further, both the Auger and photoelectron energies are also demonstrated to correlate with the same substituent constant. This fact is used to separate direct and indirect contributions to the extra-atomic relaxation.
Atomic and Molecular Physics, Advanced Chemical Physics Studies, and Optics, Physical and Theoretical Chemistry, Spectroscopy and Quantum Chemical Studies, Photochemistry and Electron Transfer Studies
Atomic and Molecular Physics, Advanced Chemical Physics Studies, and Optics, Physical and Theoretical Chemistry, Spectroscopy and Quantum Chemical Studies, Photochemistry and Electron Transfer Studies
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