Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1986 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
versions View all 2 versions
addClaim

Defect-induced hyper-Raman spectra in cubic zirconia

Authors: , Shin; , Ishigame;

Defect-induced hyper-Raman spectra in cubic zirconia

Abstract

Hyper-Raman scattering of cubic zirconia and ${\mathrm{CaF}}_{2}$ is measured at room temperature. For a ${\mathrm{CaF}}_{2}$ crystal, the frequencies of the TO and LO modes with ${T}_{1u}$ symmetry are determined to be 260 and 480 ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$, which are in good accord with the results of infrared measurements. In a fluorite-type cubic zirconia, the defect-induced hyper-Raman spectra due to the oxygen vacancies are observed. The structures of the hyper-Raman spectra are reasonably explained by the frequency distribution of hyper-Raman-active modes in the whole Brillouin zone, which is estimated from the imaginary part of the simple projections of the phonon displacement-displacement Green's functions onto a defect space consisting of an ${\mathrm{O}}_{6}$ molecule. From the analysis of the mode vectors for the ${\mathrm{O}}_{6}$ molecule, the attempt frequency of oxygen ions is found to correspond to the 690-${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ band in the observed hyper-Raman spectra with ${T}_{1u}$ symmetry.

Related Organizations
  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    34
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
34
Top 10%
Top 10%
Average
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!