
pmid: 9939343
The titanium Knight shift was measured at room temperature as a function of hydrogen concentration in TiH/sub x/ and as a function of temperature for TiH/sub 2/. In contrast to hexagonal Ti metal, the close-lying /sup 47/Ti and /sup 49/Ti resonances were resolved in TiH/sub 2/ even in the tetragonal phase. The shift in TiH/sub 2/ was found to be temperature dependent, varying from (0.252 +- 0.001)% at room temperature to (0.312 +- 0.001)% at 180 K. It was consistent with previously measured hydrogen-spin-lattice-relaxation times and with accepted band-structure models. The accuracy of the hydrogen-concentration dependence of the Knight shift was much lower due to vacancy-induced quadrupolar interactions and the resultant inability to resolve the /sup 47/Ti and /sup 49/Ti resonances. The Knight shift was only slightly concentration dependent over the entire range, having a value of about 0.25%, but jumping suddenly to 0.55% at x = 1.5. This was accompanied by a widely separated doubly peaked resonance line, We speculate on the cause of this jump and the resultant line shape.
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 13 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
