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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1978 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Effect of pressure on ionic conductivity in rubidium silver iodide and silver iodide

Authors: Paul C. Allen; David Lazarus;

Effect of pressure on ionic conductivity in rubidium silver iodide and silver iodide

Abstract

The effect of pressure on the ionic conductivity of Rb${\mathrm{Ag}}_{4}$${\mathrm{I}}_{5}$ and AgI has been measured, using single crystals and polycrystalline samples, up to pressures of 6 kbar. The activation volumes for motion in $\ensuremath{\alpha}\ensuremath{-}\mathrm{Rb}{\mathrm{Ag}}_{4}{\mathrm{I}}_{5}$ and $\ensuremath{\beta}\ensuremath{-}\mathrm{Rb}{\mathrm{Ag}}_{4}{\mathrm{I}}_{5}$, respectively, are -0.4 \ifmmode\pm\else\textpm\fi{} 0.2 and -0.2 \ifmmode\pm\else\textpm\fi{} 0.1 ${\mathrm{cm}}^{3}$/mole. In $\ensuremath{\alpha}\ensuremath{-}\mathrm{AgI}$, the motion volume increases from 0.56 \ifmmode\pm\else\textpm\fi{} 0.1 ${\mathrm{cm}}^{3}$/mole at 435 K to 0.8 \ifmmode\pm\else\textpm\fi{} 0.1 ${\mathrm{cm}}^{3}$/mole at 623 K. These values are unusually small in relation to the activation energies and are not consistent with the strain-energy model or a domain-diffusion mechanism. The logarithms of the ionic conductivities of $\ensuremath{\alpha}$- and $\ensuremath{\beta}\ensuremath{-}\mathrm{Rb}{\mathrm{Ag}}_{4}{\mathrm{I}}_{5}$ increase linearly at first and then decrease quadratically with pressure. This is related to the large quadratic pressure dependence of the second-order transition temperature $\ensuremath{\Delta}{T}_{c}(\mathrm{K})=0.141P(\mathrm{kbar})+0.111{P}^{2}({\mathrm{kbar}}^{2})$. The variation of the 122-K transition temperature with pressure is $\ensuremath{\Delta}{T}_{c}(\mathrm{K})=5.65P(\mathrm{kbar})\ensuremath{-}0.53{P}^{2}({\mathrm{kbar}}^{2})$, implying a molar volume change of ${V}_{\ensuremath{\beta}}\ensuremath{-}{V}_{\ensuremath{\gamma}}=0.37\ifmmode\pm\else\textpm\fi{}0.01$ ${\mathrm{cm}}^{3}$/mole and a change in compressibility ${K}_{\ensuremath{\beta}}\ensuremath{-}{K}_{\ensuremath{\gamma}}=(0.033\ifmmode\pm\else\textpm\fi{}0.001)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}$ ${\mathrm{cm}}^{2}$/dyn across the transition. The ionic conductivity of $\ensuremath{\gamma}\ensuremath{-}\mathrm{Rb}{\mathrm{Ag}}_{4}{\mathrm{I}}_{5}$ initially decreases with an activation volume of 9 \ifmmode\pm\else\textpm\fi{} 1 ${\mathrm{cm}}^{3}$/mole, and then levels off with increasing pressure. The negative activation volume for conduction along the $c$ axis in $\ensuremath{\beta}\ensuremath{-}\mathrm{AgI}$ has been confirmed. Both low-temperature phases have large formation volumes consistent with the theory of Rice et al. of transitions to the superionic phase.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
87
Top 10%
Top 1%
Top 10%
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