The photonic spin Hall effect of light beams reflected from the surfaces of various two-dimensional hexagonal crystalline structures, considering their associated time-reversal $\mathcal{T}$ and inversion $\mathcal{I}$ symmetries, is investigated. Employing the Haldane model with tunable parameters as a generic model, we examine the longitudinal and transverse spin-separations of the reflected beam in both topological non-trivial and trivial systems. The study reveals that the sign switching of the PSHE in these materials is attributed to the non-trivial and trivial topology. By manipulating the interplay between spin-orbit coupling and external electric fields, we demonstrate topological phase transitions in buckled Xene monolayer materials through the photonic spin Hall effect. Different behaviors of the photonic spin Hall effect are observed in various topological phases within these materials. Additionally, we explore the reflected spin and valley-polarized spatial shifts in monolayer transition metal dichalcogenides. The photonic spin Hall effect in buckled Xene monolayer materials and transition metal dichalcogenides is highly influenced by the spin and valley degrees of freedom of charge carriers, offering a promising avenue to explore spintronics and valleytronics in these hexagonal materials. We propose that the photonic spin Hall effect in Haldane materials can serve as a metrological tool for optical parameter characterization and as a promising method for determining Chern numbers and topological phase transitions through direct optical weak measurement techniques.