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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Physical Review Aarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Physical Review A
Article . 1992 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
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Kinetics of monomer-monomer surface catalytic reactions

Authors: , Krapivsky;

Kinetics of monomer-monomer surface catalytic reactions

Abstract

We study the kinetics of an irreversible monomer-monomer model of heterogeneous catalysis. In this model, two reactive species, A and B, adsorb and stick to single sites of a catalytic substrate. Surface reactions are assumed to occur only between dissimilar species that are nearest neighbors on the substrate. The kinetics of the process are studied in the reaction-controlled limit. We map the monomer-monomer model of heterogeneous catalysis onto a kinetic Ising model and find that the dynamics of the process is a superposition of zero-temperature spin-flip dynamics and infinite-temperature spin-exchange dynamics. We solve the kinetics analytically and determine the rate at which the catalyst becomes ``saturated,'' i.e., completely covered by only one species. We show that the saturation time is proportional to N ln(N), where N is the number of catalyst sites. We also discuss the monomer-monomer process with desorption.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
179
Top 10%
Top 1%
Top 10%
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