
The isotope effect in superconductors is usually summarized by giving the observed values of $p$ in the equation ${M}^{p}{T}_{c}=\mathrm{constant}$, where $M$ is the isotopic mass and ${T}_{c}$ the superconducting transition temperature. Fr\"ohlich predicted the value $p=\frac{1}{2}$, but the measurements in some instances show deviations from this prediction. An explanation of the deviation of $p$ from \textonehalf{} is offered based on an analog of Wien's displacement law applicable to the vibration spectrum of real crystal lattices. The departure of $p$ from the value \textonehalf{} is attributed to the departure of the frequency spectrum from a simple power law. For many superconducting elements, $p$ may be estimated from specific heat data, when such data are available to the desired degree of accuracy. A value of $p$ is calculated for Sn which is in good agreement with some of the experiments. The large value 0.73 observed for Pb is shown to be reasonable. The values of $p$ for the other superconducting elements are discussed. It is concluded that the observed deviations of $p$ from \textonehalf{} are not necessarily in conflict with the theories of Fr\"ohlich and Bardeen.
structure of matter
structure of matter
| selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | 10 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Top 10% | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Top 10% |
