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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1951 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Article . 1951
Data sources: zbMATH Open
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On the Formalism of Thermodynamic Fluctuation Theory

On the formalism of thermodynamic fluctuation theory
Authors: Greene, Richard F.; Callen, Herbert B.;

On the Formalism of Thermodynamic Fluctuation Theory

Abstract

From the statistical mechanical occupation probability of microstates Einstein has inferred a distribution function for the macroscopic states of a canonical ensemble. The conventional theory of thermodynamic fluctuations proceeds by making certain series expansions in the Einstein function and by dropping all cubic and higher order terms. In this paper we establish that: (a) The correlation moments for the extensive thermodynamic parameter fluctuations may be computed directly from the distribution function for the microstates, without introducing an intermediate macroscopic distribution function. (b) These same moments can be evaluated from the Einstein function without making series expansions or invoking approximations. (c) All moments computed by methods (a) or (b) agree exactly. (This may be taken as an alternative derivation of the Einstein function.) (d) The second moments computed by the conventional method are correct, but all higher moments are incorrect.

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Keywords

classical thermodynamics, heat transfer

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
127
Top 10%
Top 1%
Top 10%
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