Powered by OpenAIRE graph
Found an issue? Give us feedback
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1950 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
zbMATH Open
Article
Data sources: zbMATH Open
versions View all 2 versions
addClaim

The Lorentz Correction in Barium Titanate

The Lorentz correction in barium titanate
Authors: Slater, J. C.;

The Lorentz Correction in Barium Titanate

Abstract

It is assumed, following Devonshire, that the ferroelectric behavior of BaTi${\mathrm{O}}_{3}$ arises because of the Lorentz correction, leading to a vanishing term in the denominator of the expression for dielectric constant. If the polarizability varies slowly with temperature, the temperature variation of dielectric constant follows. This temperature variation is assumed to come from that part of the polarization resulting from the displacement of the Ti ion, in a field whose potential energy has fourth-power as well as second-power terms in the displacement. The main object of this paper is to compute the Lorentz correction exactly, not assuming spherical symmetry, but taking account of the precise crystal structure. When this is done, it is found that the Ti ions, and those oxygen ions which are in the same line with them, the line being parallel to the electric field, exert very strong fields on each other, the resulting local field at the Ti ion being much greater than if computed on the assumption of spherical symmetry. This enhanced field makes it clear that even a relatively small ionic polarizability for the Ti ions will be enough to lead to ferroelectricity. The polarization of the Ti ions is however an essential feature of the theory; if they are not polarized, the Lorentz correction is profoundly modified, leading almost exactly to the value given by the approximate theory assuming spherical symmetry, and not resulting in ferroelectricity. Detailed formulas are given for comparison of the present theory with Devonshire's results, so that the present methods can be incorporated in his treatment of the effect of elastic strain energy on the stability of the various phases below the Curie point.

Related Organizations
Keywords

Structure of matter

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    504
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 0.01%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
504
Top 1%
Top 0.01%
Top 10%
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!