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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1961 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Article . 1961
Data sources: zbMATH Open
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Thermodynamic Properties of Small Systems

Thermodynamic properties of small systems
Authors: Lebowitz, J. L.; Percus, J. K.;

Thermodynamic Properties of Small Systems

Abstract

We investigate the dependence of the pressure of a homogeneous system, at a given density $\ensuremath{\rho}$ and temperature $T$, on the number of particles $N$. The particles of the system are assumed to interact via forces of finite range $a$ and are confined to a periodic cube of volume ${L}^{3}$, $\ensuremath{\rho}\ensuremath{\equiv}\frac{N}{{L}^{3}}$. We find that there are generally two types of $N$ dependencies in the pressure and other intensive properties of the system. There is a simple dependence which goes essentially as a power series in ($\frac{1}{N}$) and may be computed explicitly in terms of the grand-ensemble averages of these properties where it is absent. The other, more complex, dependence comes from the volume dependence of those cluster integrals which are large enough to wind at least once around the periodic torus. These do not appear in a virial expansion for terms $k\ensuremath{\le}{(\frac{N}{\ensuremath{\rho}{a}^{3}})}^{\frac{1}{3}}$. They play however a dominant role in the $N$ dependence observed by Alder and Wainwright in their machine computations on a hard-sphere gas. While the explicit calculation of these terms is very difficult and has been carried through only in a few special cases, they may be related, approximately at least, to the radial distribution function in an infinite system. We also find an expression for the correlation between the particles of an ideal gas represented by a microcanonical ensemble.

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Keywords

mechanics of particles and systems

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
116
Top 1%
Top 0.1%
Top 10%
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