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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
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https://doi.org/10.1103/physre...
Article . 1959 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Article . 1959
Data sources: zbMATH Open
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On the Quantum Theory of the Third Virial Coefficient

On the quantum theory of the third virial coefficient
Authors: Pais, A.; Uhlenbeck, G. E.;

On the Quantum Theory of the Third Virial Coefficient

Abstract

The quantum theory of the third virial coefficient $C$ is discussed. Three types of intermolecular pair forces must be distinguished. (1) No bound or low-lying two- and/or three-body states exist. The first four terms of the low-temperature expansion of ${C}_{\mathrm{BE}}$ are obtained. They depend on the scattering length, the effective range, and a third length which cannot be inferred from scattering data. The limitations of the applicability of such expansions are discussed, both for ${\mathrm{He}}^{4}$ and ${\mathrm{He}}^{3}$, by means of a comparison of the corresponding expansion for the second virial coefficient $B$ with detailed numerical results known for specific potentials. (2) Existence of a near zero energy level both for the two- and the three-body system. It is shown how in this case the actual potentials may be replaced by suitably matched boundary conditions on the two- and the three-body wave functions near the respective coordinate origins. It is first explained how the method applies to $B$. Then the leading term of $C$ is explicitly determined. (3) Existence of strongly bound two- and three-body states. An approximate expression for $C$ is given by treating the single atoms and the binary and ternary compounds as a system of three ideal gases in chemical equilibrium.

Keywords

mechanics of particles and systems

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
85
Top 10%
Top 1%
Average
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