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https://doi.org/10.1103/physre...
Article . 1958 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
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Article . 1958
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Correlation Energy of a Free Electron Gas

Correlation energy of a free electron gas
Authors: Nozières, P.; Pines, D.;

Correlation Energy of a Free Electron Gas

Abstract

The limits of validity of the correlation-energy calculations in the regions of high density, low density, and actual metallic electron densities are discussed. Simple physical arguments are given which show that the high-density calculation of Gell-Mann and Brueckner is valid for ${r}_{s}\ensuremath{\lesssim}1$ while the low-density calculation of Wigner is valid for ${r}_{s}\ensuremath{\gtrsim}20$. For actual metallic densities it is shown that the contribution to the correlation energy from long-wavelength momentum transfers ($kl\ensuremath{\beta}{k}_{0}l0.47{{r}_{s}}^{\frac{1}{2}}{k}_{0}$) may be accurately calculated in the random phase approximation. This contribution is calculated using the Bohm-Pines extended Hamiltonian, and is shown to be $E(\ensuremath{\beta})=\left(\ensuremath{-}0.458\frac{{\ensuremath{\beta}}^{2}}{{r}_{s}}+0.866\frac{{\ensuremath{\beta}}^{3}}{{{r}_{s}}^{\frac{3}{2}}}\ensuremath{-}0.98\frac{{\ensuremath{\beta}}^{4}}{{{r}_{s}}^{2}}\right)\left(+0.019\frac{{\ensuremath{\beta}}^{4}}{{r}_{s}}+0.706\frac{{\ensuremath{\beta}}^{5}}{{{r}_{s}}^{\frac{5}{2}}}+\ensuremath{\cdots}\right)\mathrm{ry}.$ An identical result is obtained by a suitable expansion of the result of Gell-Mann and Brueckner; the validity of the Bohm-Pines neglect of subsidiary conditions in the calculation of the ground-state energy is thereby explicitly established. The contribution to the correlation energy from sufficiently high momentum transfers ($k\ensuremath{\gtrsim}{k}_{0}$) will arise only from the interaction between electrons of antiparallel spin, and may be estimated using second-order perturbation theory. The contribution arising from intermediate momentum transfers ($0.47{{r}_{s}}^{\frac{1}{2}}{k}_{0}\ensuremath{\lesssim}k\ensuremath{\lesssim}{k}_{0}$) cannot be calculated analytically; the interpolation procedures for this domain proposed by Pines and Hubbard are shown to be nearly identical, and their accuracy is estimated as \ensuremath{\sim}15%. The result for the over-all correlation energy using the interpolation procedure of Pines is ${E}_{c}\ensuremath{\cong}(\ensuremath{-}0.115+0.031\mathrm{ln}{r}_{s})\mathrm{ry}.$

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quantum theory

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
570
Top 0.1%
Top 0.01%
Top 10%
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