
Intermolecular features in atomic force microscopy (AFM) images of organic molecules have been ascribed to intermolecular bonds. A recent theoretical study [P. Hapala et al., Phys. Rev. B 90, 085421 (2014)] showed that these features can also be explained by the flexibility of molecule terminated tips. We probe this effect by carrying out AFM experiments on a model system that contains regions where intermolecular bonds should and should not exist between close-by molecules. Intermolecular features are observed in both regions, demonstrating that intermolecular contrast cannot be directly interpreted as intermolecular bonds.
hydrogen bond, ta214, non-contact atomic force microscopy (AFM), ta114, Condensed Matter - Mesoscale and Nanoscale Physics, ta221, FOS: Physical sciences, carbon monoxide (CO) -terminated tip, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), intermolecular contrast, ta218
hydrogen bond, ta214, non-contact atomic force microscopy (AFM), ta114, Condensed Matter - Mesoscale and Nanoscale Physics, ta221, FOS: Physical sciences, carbon monoxide (CO) -terminated tip, Mesoscale and Nanoscale Physics (cond-mat.mes-hall), intermolecular contrast, ta218
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