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Structure and local variations of the graphene moiré on Ir(111)

Authors: Hämäläinen, Sampsa; Boneschanscher, M.P.; Jacobse, P.H.; Swart, I.; Pussi, K.; Moritz, W.; Lahtinen, J.; +3 Authors

Structure and local variations of the graphene moiré on Ir(111)

Abstract

We have studied the incommensurate moir�� structure of epitaxial graphene grown on iridium(111) by dynamic low energy electron diffraction [LEED-I(V)] and non-contact atomic force microscopy (AFM) with a CO terminated tip. Our LEED-I(V) results yield the average positions of all the atoms in the surface unit cell and are in qualitative agreement with the structure obtained from density functional theory (DFT). The AFM experiments reveal local variations of the moir�� structure: the corrugation varies smoothly over several moir�� unit cells between 42 and 56 pm. We attribute these variations to the varying registry between the moir�� symmetry sites and the underlying substrate. We also observe isolated outliers, where the moir�� top sites can be offset by an additional 10 pm. This study demonstrates that AFM imaging can be used to directly yield the local surface topography with pm accuracy even on incommensurate 2D structures with varying chemical reactivity.

Countries
Finland, Netherlands
Keywords

DECOMPOSITION, Condensed Matter - Materials Science, SPECTROSCOPY, ta214, Ir(111), ta114, HEXAGONAL BORON-NITRIDE, SUPERLATTICES, ta221, graphene, SCANNING-TUNNELING-MICROSCOPY, STM, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, iridium, NANOMESH, RU(0001), LEED-I(V), moiré, AFM, ta218

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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    57
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
57
Top 10%
Top 10%
Top 10%
Green
bronze