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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao https://doi.org/10.1...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1103/physre...
Article . 1998 . Peer-reviewed
License: APS Licenses for Journal Article Re-use
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Long-livedMn2+emission in nanocrystallineZnS:Mn2+

Authors: Ageeth A. Bol; Andries Meijerink;

Long-livedMn2+emission in nanocrystallineZnS:Mn2+

Abstract

Recently, it has been reported that doped semiconductor nanoparticles can yield both high luminescence efficiencies and a spectacular lifetime shortening, which suggests that doped semiconductor nanoparticles form a new class of luminescent materials for various applications. From lifetime measurements and time-resolved spectroscopy we conclude that the ${\mathrm{Mn}}^{2+}$ emission does not show a spectacular shortening of the decay time upon decreasing particle size as reported earlier. The luminescence of nanocrystalline ${\mathrm{Z}\mathrm{n}\mathrm{S}:\mathrm{M}\mathrm{n}}^{2+}$ indeed has a short decay time (\ensuremath{\sim}100 ns), but also shows a long ms range decay time. The short decay time is ascribed to a defect-related emission of ZnS, and is not from the decay of the ${}^{4}{\mathrm{T}}_{1}{\ensuremath{-}}^{6}{\mathrm{A}}_{1}$ transition of the ${\mathrm{Mn}}^{2+}$ impurity as suggested by other authors. The ${}^{4}{\mathrm{T}}_{1}{\ensuremath{-}}^{6}{\mathrm{A}}_{1}$ transition of the ${\mathrm{Mn}}^{2+}$ has a ``normal'' decay of about 1.9 ms. Based on our observations, we conclude that doped semiconductor nanoparticles do not form a new class of luminescent materials, combining a high efficiency with a short (ns) decay time.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
399
Top 1%
Top 1%
Top 1%
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