Ductile yielding of rocks and similar solids localize shear zones, which often show complex internal structures due to the networking of their secondary shear bands. Combining observations from naturally deformed rocks and numerical modelling, this study addresses the following crucial question: What dictates the internal shear bands to network during the evolution of an initially homogeneous ductile shear zone? Natural shear zones, observed in the Chotonagpur Granite Gneiss Complex of the Precambrian craton of Eastern India, show characteristic patterns of their internal shear band structures, classified broadly into three categories: type I (network of antithetic low-angle Riedel (R) and synthetic P-bands), type II (network of shear-parallel C and P/R bands) and type III (distributed shear domains containing isolated undeformed masses). Considering strain-softening rheology, our two-dimensional viscoplastic models reproduce these three types, allowing us to predict the condition of shear band growth with a specific network pattern as a function of the following parameters: normalized shear zone thickness, bulk shear rate and bulk viscosity. This study suggests that complex anastomosing shear-band structures can evolve under simple shear kinematics in the absence of any pure shear component.