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New Journal of Physics
Article . 2020 . Peer-reviewed
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New Journal of Physics
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A Kretschmann setup at acoustic frequencies for studying molecular vibration

Authors: Giuseppina Simone; Pim de Ruijter; Pim de Ruijter;

A Kretschmann setup at acoustic frequencies for studying molecular vibration

Abstract

Abstract In this study, simultaneous measurement of surface plasmon resonance (SPR) and surface enhanced Raman scattering (SERS) on flat metallic surfaces was demonstrated in a setup based on the Kretschmann configuration at acoustic frequency. This asset facilitates matching the photon and the surface plasmon polaritons wavevectors by tunneling the photon in the total internal reflection geometry and we demonstrate the compensation for the absence of hotspots typical on rough surfaces. The optomechanical asset allows detecting the two signals and prevents their interference. Experimental and numerical analyses were done for characterizing the two signals. The results emphasize the enhancement of the electromagnetic field at the surface, which provides high sensitivity for detecting the signals coming from the Raman probe molecules such as Congo red and thiols such as cysteamine. The combination of simultaneous SPR–SERS microspectroscopy at low frequencies opens up interesting prospects that facilitate experimental conditions using standard SPR setups, with a dramatic reduction in sensor cost.

Related Organizations
Keywords

acoustic frequency, frequency domain processing, Science, Physics, QC1-999, Q, flat Au, SPR/SERS, molecular vibration

  • BIP!
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    citations
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    9
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Average
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Average
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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Top 10%
Average
Average
gold