The chiral structure of supersymmetric particle couplings involving third generation Standard Model fermions depends on left-right squark and slepton mixings as well as gaugino-higgsino mixings. The shapes and intercorrelations of invariant mass distributions of a first or second generation lepton with bottoms and taus arising from adjacent branches of SUSY cascade decays are shown to be a sensitive probe of this chiral structure. All possible cascade decays that can give rise to such correlations within the MSSM are considered. For bottom-lepton correlations the distinctive structure of the invariant mass distributions distinguishes between decays originating from stop or sbottom squarks through either an intermediate chargino or neutralino. For decay through a chargino the spins of the stop and chargino are established by the form of the distribution. When the bottom charge is signed through soft muon tagging, the structure of the same-sign and opposite-sign invariant mass distributions depends on a set function of left-right and gaugino-higgsino mixings, as well as establishes the spins of all the superpartners in the sequential two-body cascade decay. Tau-lepton and tau-tau invariant mass distributions arising from MSSM cascade decays are likewise systematically considered with particular attention to their dependence on tau polarization. All possible tau-lepton and tau-tau distributions are plotted using a semi-analytic model for hadronic one-prong taus. Algorithms for fitting tau-tau and tau-lepton distributions to data are suggested.

35 pages, 17 .eps figures