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Line broadening studies for Cr3+pairs and single ions in different oxide lattices

Authors: M. A. de Bruin; A.P. Vink; Andries Meijerink;

Line broadening studies for Cr3+pairs and single ions in different oxide lattices

Abstract

The electron-phonon coupling for Cr3+ in different oxide host lattices (MgO, α-Al2O3 and LaAlO3) was probed by performing temperature dependent line broadening measurements for zero-phonon emission lines of single ions and exchange coupled pairs. No differences in electron-phonon coupling were found comparing the results for pairs and single ions in α-Al2O3 (3NN and 4NN pairs) and LaAlO3 (NN pairs). In Cr3+ doped MgO (Cr3+-VMg-Cr3+ pairs), it was found that the electron-phonon coupling strength parameter is larger for the pairs than for the isolated Cr3+ ions. This is probably due to changes in the surroundings of Cr3+ by local charge compensation by a magnesium vacancy, and not to interaction between the Cr3+ ions.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
16
Top 10%
Top 10%
Average
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