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The Astrophysical Journal
Article . 1984 . Peer-reviewed
Data sources: Crossref
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The relative abundances of cyanogenated molecules

Authors: E. Churchwell; A. G. Nash; C. M. Walmsley;

The relative abundances of cyanogenated molecules

Abstract

We have observed with approximately the same spatial resolution HCN (J = 1-0), HNC (J = 1-0), their /sup 13/C isotopic species, and HC/sub 3/N (J = 2-1 and J = 10-9) toward six locations in the Taurus dark cloud complex, one dark cloud (L183) outside Taurus, and two warm clouds with associated H II regions. The column densities of HCN, HNC, and HC/sub 3/N are typically less than those of NH/sub 3/ by factors of 10/sup -1/-10/sup -3/. NH/sub 3/ is believed to be a tracer of the total H/sub 2/ abundance and a chemical precursor of the cyanogenated molecules. HNC is systematically about a factor of 10 more abundant than HC/sub 3/N. Limits on HCN column densities are given; upper limits were determined by limits on H/sup 13/CN emission, and lower limits were derived from the weakest hyperfine component, F = 0-1, of HCN (J = 1-0). The HNC/HCN column-density ratios lie in the range approx.3 to approx.10 in cold dark clouds. They are uncertain because HCN column densities are uncertain, but they are definitely greater than unity. The fact that this ratio does not deviate by large factors from unity can be understood in a gas-phase chemicalmore » network if ''chemical shuffling'' between HNC and HCN is important. Inclusion of reactions that convert HCN to HNC and vice versa forces the ratio HNC/HCN to a narrow range about unity if the chemical shuffling rates are fast relative to other HCN and HNC destruction rates.« less

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
28
Top 10%
Top 10%
Average
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