Mitigation of urban air pollution is a big challenge, especially for the metropolitan cities of the world. In an Indian metropolis like Delhi, even after the implementation of several control policies, no such remarkable change has been observed in its air quality. Globally, afforestation or greenbelt development is an effective and well-recognized pollution abatement process. The aim of our present study was to examine the biochemical response of some naturalized ornamental plant species, viz. Dracaena deremensis, Tagetes erecta, Rosa indica and Dianthus caryophyllus. During experimental study, plants were kept at selected sites which were categorized in terms of traffic density (emission source) and vegetative pattern during winter months for 120 days. Four biochemical parameters, viz. total chlorophyll, ascorbic acid, pH, relative water contents along with Air Pollution Tolerance Indices were determined from foliar samples at each selected site. D. deremensis and T. erecta were classified under tolerant while R. indica and D. caryophyllus were marked as in sensitive category. Based on the sensitivity of selected plant species, it has been recommended that D. deremensis and T. erecta may be used as sinks for the abatement of air pollution at highly polluted sites whereas R. indica and D. caryophyllus can be used as bioindicators.