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Vibronic transitions in rare earth spectroscopy

Authors: G. Blasse;

Vibronic transitions in rare earth spectroscopy

Abstract

Abstract An overview of the studies of vibronic transitions in the rare earth ions is given with special attention to the intraconfigurational transitions. First the general theory is shortly reviewed, later that of the rare-earth vibronic transitions. The vibronic spectroscopy of Gd3+ is extensively dealt with, because it is an ideal ion for this type of study due to its non-degenerate ground state. Vibronic coupling with several vibrational modes has been observed, also with modes in which the central ion is not directly involved. Attention has also been given to Eu3+ and Pr3+and some other specific cases of interest. The use of Gd3+ as a probe ion is pointed out. A comparison with relating physical phenomena is made. The experimental results are compared with the theoretical expressions derived up till now. The agreement is satisfactory, although of a qualitative nature. The concentration dependence of the vibronic intensity is not well understood. The role of opposite-parity configurations is probably...

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
129
Top 10%
Top 1%
Top 10%
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