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Synthesis and Reacti...arrow_drop_down

Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry

Article . 1981 . Peer-reviewed

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Lanthanon(III) Amido Complexes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1981 English Publisher:Informa UK LimitedJournal:Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, volume 11, pages 267-278 (issn: 0094-5714, eissn: 1532-2440,

Authors: A. M. Bhandari; Ashok K. Solanki;

doi: 10.1080/00945718108059302

Lanthanon(III) Amido Complexes

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Abstract

Abstract Ln(NHCOR)3 (I) and Ln(SCNHCH3)3 (II) are prepared and characterized by elemental analysis, electronic and infrared spectra (Ln = La, Pr, Nd, Sm; R = CH3, C6H5, C5H4N). The bonding of matal to amide is through nitrogen in I while it is through sulphur in II. Electronic spectra indicate development of covalant character of bonding in these compounds. Thermogravimetric studies of the acetamido complexes are reported.

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Jai Narain Vyas University
India

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