Models for Taxol Biosynthesis: SeO2Oxidation of Taxadiene

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 2006 English Publisher:Informa UK LimitedJournal:Synthetic Communications, volume 36, pages 2,577-2,585 (issn: 0039-7911, eissn: 1532-2432,

Authors: Howard J. Williams; James D. Pennington; Qiulong Huang; A. Ian Scott;

doi: 10.1080/00397910600764121

Models for Taxol Biosynthesis: SeO2Oxidation of Taxadiene

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Abstract

Abstract Together with the expected mono‐oxidized taxa‐4(20),11(12)‐diene‐5‐ol (1) and taxa‐4(5),11,20‐diene‐20‐ol (2), a new taxane skeleton, 3,12‐cyclotaxane (3), was obtained from chemical oxidation of taxadiene by selenium dioxide/t‐butylhydroperoxide.

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