Synthesis of the Androgen-Receptor Antagonists (±)-Ws9761 A and B

descriptionPublicationkeyboard_double_arrow_right Article 01 May 1996 English Publisher:CSIRO PublishingJournal:Australian Journal of Chemistry, volume 49, pages 617-624 (issn: 0004-9425, eissn: 1445-0038,

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Authors: DW Cameron; CE Skene;

doi: 10.1071/ch9960617

Synthesis of the Androgen-Receptor Antagonists (±)-Ws9761 A and B

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Abstract

The non-steroidal androgen-receptor antagonists WS9761 A (1,6,10-trihydroxy-2,8,10-trimethylanthrone) and WS9761 B (1,6,10-trihydroxy-2-hydroxymethyl-8,10-dimethylanthrone) were synthesized for the first time in racemic form by using Diels-Alder methodology followed by regioselective Grignard addition.

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